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Low Molecular-Mass Organic Gelators

Low Molecular-Mass Organic Gelators

Автор: Jesse Russell,Ronald Cohn, 101 стр., издатель: "Книга по Требованию", ISBN: 978-5-5082-8733-7

High Quality Content by WIKIPEDIA articles! Low Molecular-Mass Organic Gelators (LMOGs) are a relatively new and dynamic soft materials capable of numerous possible applications; LMOGs are the monomeric sub-unit which form self-assembled fibrillar networks (SAFINs) that entrap solvent between the strands. SAFINs arise from the formation of strong non-covalent interactions between LMOG monomeric sub-units. As SAFINs are forming, the long fibers become intertwined and trap solvent molecules. Once solvent molecules are entrapped within the network, they are immobilized by surface tension effects. The stability of a gel is dependent on the equilibrium between the assembled network and the dissolved gelators. One characteristic of an LMOG, that demonstrates its stability, is its ability to contain an organic solvent at the boiling point of that solvent due to extensive solvent-fibrillar interactions. Gels self-assemble through non-covalent interactions such as ?-stacking, hydrogen-bonding,...
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