High Quality Content by WIKIPEDIA articles! A sigmatropic reaction in organic chemistry is a Pericyclic reaction wherein the net result is one ?-bond is changed to another ?-bond in an uncatalyzed intramolecular process. The name sigmatropic is the result of a compounding of the long-established sigma designation from single carbon-carbon bonds and the Greek word tropos, meaning turn. In this type of rearrangement reaction, a substituent moves from one part of a ?-bonded system to another part in an intramolecular reaction with simultaneous rearrangement of the ? system. True sigmatropic reactions are usually uncatalyzed, although Lewis acid catalysis is possible. Sigmatropic reactions often have transition-metal catalysts that form intermediates in analogous reactions. The most well-known of the sigmatropic rearrangements are the Cope rearrangement, Claisen rearrangement, Carroll rearrangement and the Fischer indole synthesis. Данное издание представляет собой компиляцию сведений,...

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