Trimethylindium
Автор:
Jesse Russell,Ronald Cohn, 96 стр., издатель:
"Книга по Требованию", ISBN:
978-5-5113-1093-0
High Quality Content by WIKIPEDIA articles! Trimethylindium (abbr: TMI or TMIn), In(CH3)3, (CAS #: 3385-78-2) is the preferred metalorganic source of Indium for metalorganic vapour phase epitaxy (MOVPE) of indium-containing compound semiconductors, such as InP, InAs, InN, InSb, GaInAs, InGaN, AlGaInP, AlInP, AlInGaNP etc. TMI is a white, crystalline and sublimable solid, with melting point 88 °C. TMI is known to be pyrophoric, i.e. it ignites sponteneously upon contact with air; and its decomposition is often found to be uncontrollable as the temperature of its surrounding exceeds its melting point (i.e. > 88°C) and reaches 101 °C and above. TMI is also reported to exhibit autocatalytic behavior during its thermal decomposition. Hence TMI needs to be handled with utmost care and caution, e.g. stored in preferably cool, dry place at 0-25°C, and operating temperatures not to exceed 50 °C to avoid deterioration. TMI is also known to react extremely violently with oxidizers and...